Usuário(a):Wilkruvic/Testes1

O modelo Ising ( /ˈaɪsɪŋ/; alemão: [ˈiːzɪŋ]), que recebe este nome em homenagem ao físico Ernst Ising, é um modelo matemático de ferromagnetismo em mecânica estatística. O modelo consiste em variáveis discretas que representam os momentos de dipolo magnético de spins atômicos que podem estar um de dois estados ($+1$ ou $-1$). Os spins são dispostos em um grafo, geralmente um reticulado, permitindo que cada spin interaja com seus vizinhos. O modelo permite a identificação de transições de fase, como um modelo simplificado da realidade. O modelo Ising bidimensional de reticulado quadrado é um dos mais simples modelos estatísticos para mostrar uma transição de fase.

O modelo Ising foi inventado pelo físico Wilhelm Lenz, que o deu como um problema ao seu aluno Ernst Ising. O modelo Ising unidimensional não tem transição de fase e foi resolvido pelo próprio Ising em sua tese de 1924. O modelo Ising bidimensional de reticulado quadrado é muito mais complexo e recebeu uma descrição analítica muito tempo depois por Lars Onsager. É geralmente resolvido por um método de matriz de transferência, ainda que existam abordagens diferentes, mais próximas da teoria quântica de campos.

Em mais de quatro dimensões, a transição de fase do modelo Ising é descrita pela teoria de campo médio.

Definição

Considere um conjunto $\Lambda$ de locais de reticulado, cada um com um conjunto de locais adjacentes (isto é, um grafo) formando um reticulado de $d$ dimensões. Para cada local de reticulado $k\in \Lambda$, há uma variável discreta $\sigma _{k}$, tal que $\sigma _{k}\in \{-1,+1\}$, representando o spin do local. Uma configuração de spin, $\sigma =(\sigma _{k})_{k\in \lambda }$ é uma atribuição de valor de spin para cada local de reticulado.

Para quaisquer dois locais adjacentes $i,j\in \Lambda$, há uma interação $J_{ij}$. Além disso, um local $j\in \Lambda$ tem um campo magnético externo $h_{j}$ interagindo com ele. A energia de uma configuração $\sigma$ é dada por uma função hamiltoniana

$H(\sigma )=-\sum _{\langle i~j\rangle }J_{ij}\sigma _{i}\sigma _{j}-\mu \sum _{j}h_{j}\sigma _{j}$

em que a primeira soma é de pares de spins adjacentes (cada par é contado uma vez). A notação $ij$ indica que os locais $i$ e $j$ são os vizinhos mais próximos. O momento magnético é dado por $\mu$. Perceba que o sinal no segundo termo da hamiltoniana acima deveria ser na verdade positivo porque o momento magnético do elétron é antiparalelo ao seu spin, mas o termo negativo é usado convencionalmente. A probabilidade de configuração é dada pela distribuição de Boltzmann com temperatura inversa $\beta \geq 0$:

$P_{\beta }(\sigma )={e^{-\beta H(\sigma )} \over Z_{\beta }},$

em que $\beta =(k_{\beta }T)^{-1}$

e a constante de normalização

$Z_{\beta }=\sum _{\sigma }e^{-\beta H(\sigma )}$

é a função de partição. Para uma função $f$ dos spins ("observáveis"), denota-se por

$\langle f\rangle _{\beta }=\sum _{\sigma }f(\sigma )P_{\beta }(\sigma )\,$

a expectativa (valor médio) de $f$.

As probabilidades de configuração $P_{\beta }(\sigma )$ representam a probabilidade de estar em um estado com configuração $\sigma$ em equilíbrio.

Discussão

O sinal de menos em cada termo da função hamiltoniana $H(\sigma )$ é convencional. Usando esta convenção de sinal, os modelos Ising podem ser classificados de acordo com o sinal da interação: se, para todos os pares $i,j$

$J_{ij}>0$, a interação é chamada de ferromagnética;

$J_{ij}<0$, a interação é chamada de antiferromagnética;

$J_{ij}=0$, os spins são não interativos.

De outro modo, o sistema é chamado de não ferromagnético.

Em um modelo Ising ferromagnético, os spins desejam estar alinhados: as configurações em que os spins adjacentes são do mesmo sinal têm uma probabilidade mais alta. Em um modelo antiferromagnético, os spins adjacentes tendem a ter sinais opostos.

A convenção de sinal de $H(\sigma )$ também explica como um local $j$ de spin interage com o campo externo. Nomeadamente, o local de spin quer ficar alinhado com o campo externo. Se:

$h_{j}>0$, o local $j$ de spin deseja se alinhar na direção positiva;

$h_{j}<0$, o local $j$ de spin deseja se alinhar na direção negativa;

$h_{j}=0$, não há influência externa no local de spin.

Simplificações

Modelos Ising são frequentemente examinados sem um campo externo interagindo com o reticulado, isto é, $h=0$ para qualquer $j$ no reticulado $\Lambda$. Usando esta simplificação, a hamiltoniana se torna:

$H(\sigma )=-\sum _{\langle i~j\rangle }J_{ij}\sigma _{i}\sigma _{j}.$

Quando o campo externo é zero em todo lugar, $h=0$, o modelo Ising é simétrico sob comutação do valor do spin em todos os locais de reticulado; um campo diferente de zero quebra esta simetria.

Outra simplificação comum é assumir que todos os vizinhos mais próximos $ij$ têm a mesma forma de interação. Então, podemos afirmar que $J_{ij}=J$ para todos os pares $i,j$ em $\Lambda$. Neste caso, a hamiltoniana é ainda mais simplificada, tornando-se:

$H(\sigma )=-J\sum _{\langle i~j\rangle }\sigma _{i}\sigma _{j}.$

Questões

Um número significativo de questões estatísticas que podem ser feitas sobre este modelo estão no limite dos grandes números de spins:

• Em uma configuração típica, a maior parte dos spins é $+1$ ou $-1$ ou estão divididos igualmente?
• Se um spin em qualquer posição dada $i$ for $1$, qual é a probabilidade de que o spin na posição $j$ seja também $1$?
• Se $\beta$ for mudada, há transição de fase?
• Em um reticulado $\Lambda$, qual é a dimensão fractal da forma de um grande grupo de spins $+1$?

Propriedades básicas e histórico

Visualization of the translation-invariant probability measure of the one-dimensional Ising model.

O caso mais estudado do modelo Ising é o modelo invariante por translação ferromagnético de campo zero em um reticulado de $d$ dimensões, nomeadamente, $\Lambda =Z^{d}$, $J_{ij}=1$, $h=0$.

Em sua tese de doutorado de 1924, Ising resolveu o modelo para o caso $d=1$, que pode ser pensado como um reticulado horizontal linear em que cada local apenas interage com seus vizinhos à esquerda e à direita. Em uma dimensão, a solução não admite transição de fase. Nomeadamente, para qualquer $\beta$, as correlações $\sigma _{i}\sigma _{j}$ decaem exponencialmente em $|i-j|$:

$\langle \sigma _{i}\sigma _{j}\rangle _{\beta }\leq C\exp(-c(\beta )|i-j|),\,$

e o sistema fica desordenado. Na base deste resultado, ele incorretamente concluiu que este modelo não exibe comportamento de fase em qualquer dimensão.

O modelo Ising se submete a uma transição de fase entre uma fase ordenada e uma fase desordenada em duas dimensões ou mais. Nomeadamente, o sistema fica desordenado para pequeno $\beta$, enquanto, para grande $\beta$, o sistema exibe ordem ferromagnética:

$\langle \sigma _{i}\sigma _{j}\rangle _{\beta }\geq c(\beta )>0.\,$

Isto foi provado pela primeira vez pelo físico teuto-britânico Rudolf Peierls em 1936, usando o que é chamado atualmente de argumento de Peierls.

O modelo Ising em um reticulado quadrado bidimensional sem campo magnético foi analiticamente resolvido por Lars Onsager. O físico-químico norueguês mostrou que as funções de correlação e a energia livre termodinâmica são determinadas por um férmion de reticulado não interagente. Onsager anunciou a fórmula para a magnetização espontânea para o modelo bidimensional em 1949, mas não deu uma derivação. Yang deu a primeira prova pública desta fórmula, usando uma fórmula de limite para determinantes de Fredholm, provada em 1951 por Gábor Szegő em resposta direta ao trabalho de Onsager.

Significância histórica

Um dos argumentos de Demócrito em favor do atomismo era de que os átomos naturalmente explicam os limites de fase aguda observados nos materiais, como quando o gelo derrete e se torna água líquida ou como quando a água líquida se torna vapor. Sua ideia era de que pequenas mudanças em propriedades de escala atômica levariam a grandes mudanças no comportamento agregado. Outros acreditavam que a matéria é inerentemente contínua, não atômica, e que propriedades de larga escala não são redutíveis a propriedades atômicas básicas.

Enquanto as leis de ligação química deixaram claro aos químicos do século XIX que os átomos eram reais, entre os físicos, o debate continuou até o começo do século XX. Atomistas, notavelmente James Clerk Maxwell e Ludwig Boltzmann, aplicaram a formulação de Hamilton das leis de Newton a grandes sistemas e descobriram que o comportamento estatístico dos átomos descrevia corretamente gases em temperatura ambiente. No entanto, a mecânica estatística clássica não levava em conta todas as propriedades de líquidos e sólidos, nem de gases a baixas temperaturas.

Uma vez que a moderna mecânica quântica foi formulada, o atomismo não estava mais em conflito com a experiência, mas isto não levou a uma aceitação universal da mecânica estatística, que ia além do atomismo. Josiah Willard Gibbs havia dado um completo formalismo para reproduzir as leis da termodinâmica a partir das leis da mecânica. Contudo, vários argumentos falhos sobreviveram ao século XIX, quando a mecânica estatística era considerada duvidosa. Os lapsos na intuição se originavam em sua maioria do fato de que o limite de um sistema estatístico infinito tem muitas leis zero-um ausentes em sistemas finitos: uma mudança infinitesimal em um parâmetro pode levar a grandes diferenças comportamento geral, agregado, como Demócrito esperava.

Sem transições de fase em volume finito

Na parte inicial do século XX, alguns acreditavam que a função de partição nunca poderia descrever uma transição de fase com base no seguinte argumento:

1. A função de partição é uma soma de $e^{-\beta E}$ sobre todas as configurações.
2. A função exponencial é analítica em todo lugar como uma função de $\beta$.
3. A soma de funções analíticas é uma função analítica.

Este argumento funciona para uma soma finita de exponenciais e estabelece corretamente que não há singularidades na energia livre de um sistema de tamanho finito. Para sistemas que estão no limite termodinâmico (isto é, para sistemas infinitos), a soma infinita pode levar a singularidades. A convergência ao limite termodinâmico é rápida, de modo que o comportamento de fase é aparente já em um reticulado relativamente pequeno, ainda que as singularidades sejam suavizadas pelo tamanho finito do sistema.

Isto foi estabelecido pela primeira vez por Peierls no modelo Ising.

Gotículas de Peierls

Logo depois que Lenz e Ising construíram o modelo Ising, Peierls foi capaz de mostrar explicitamente que uma transição de fase ocorre em duas dimensões.

Para fazer isto, ele comparou os limites de alta temperatura e baixa temperatura. A uma temperatura infinita, $\beta =0$

To do this, he compared the high-temperature and low temperature limits. At infinite temperature, β = 0, all configurations have equal probability. Each spin is completely independent of any other, and if typical configurations at infinite temperature are plotted so that plus/minus are represented by black and white, they look like television snow. For high, but not infinite temperature, there are small correlations between neighboring positions, the snow tends to clump a little bit, but the screen stays random looking, and there is no net excess of black or white.

A quantitative measure of the excess is the magnetization, which is the average value of the spin:

$M={1 \over N}\sum _{i=1}^{N}S_{i}.$

A bogus argument analogous to the argument in the last section now establishes that the magnetization in the Ising model is always zero.

1. Every configuration of spins has equal energy to the configuration with all spins flipped.
2. So for every configuration with magnetization M there is a configuration with magnetization −M with equal probability.
3. The system should therefore spend equal amounts of time in the configuration with magnetization M as with magnetization -M.
4. So the average magnetization (over all time) is zero.

As before, this only proves that the average magnetization is zero at any finite volume. For an infinite system, fluctuations might not be able to push the system from a mostly-plus state to a mostly minus with a nonzero probability.

For very high temperatures, the magnetization is zero, as it is at infinite temperature. To see this, note that if spin A has only a small correlation ε with spin B, and B is only weakly correlated with C, but C is otherwise independent of A, the amount of correlation of A and C goes like ε². For two spins separated by distance L, the amount of correlation goes as ε^L but if there is more than one path by which the correlations can travel, this amount is enhanced by the number of paths.

The number of paths of length L on a square lattice in d dimensions is

$N(L)=(2d)^{L}$

since there are 2d choices for where to go at each step.

A bound on the total correlation is given by the contribution to the correlation by summing over all paths linking two points, which is bounded above by the sum over all lengths paths of length L divided by

$\sum _{L}(2d)^{L}(\varepsilon )^{L}$

which goes to zero when ε is small.

At low temperatures, β ≫ 1, the configurations are near the lowest energy configuration, the one where all the spins are plus or all the spins are minus. Peierls asked whether it is statistically possible at low temperature, starting with all the spins minus, to fluctuate to a state where most of the spins are plus. For this to happen, droplets of plus spin must be able to congeal to make the plus state.

The energy of a droplet of plus spins in a minus background is proportional to the perimeter of the droplet L, where plus spins and minus spins neighbor each other. For a droplet with perimeter L, the area is somewhere between (L − 2)/2 (the straight line) and (L/4)² (the square box). The probability cost for introducing a droplet has the factor e^−βL, but this contributes to the partition function multiplied by the total number of droplets with perimeter L, which is less than the total number of paths of length L:

$N(L)<4^{2L}.$

So that the total spin contribution from droplets, even overcounting by allowing each site to have a separate droplet, is bounded above by

$\sum _{L}L^{2}4^{-2L}e^{-4\beta L}$

which goes to zero at large β. For β sufficiently large, this exponentially suppresses long loops, so that they cannot occur, and the magnetization never fluctuates too far from −1.

So Peierls established that the magnetization in the Ising model eventually defines superselection sectors, separated domains which are not linked by finite fluctuations.

Kramers–Wannier duality

Ver artigo principal: Kramers–Wannier duality

Kramers and Wannier were able to show that the high temperature expansion and the low temperature expansion of the model are equal up to an overall rescaling of the free energy. This allowed the phase transition point in the two-dimensional model to be determined exactly (under the assumption that there is a unique critical point).

Yang–Lee zeros

Ver artigo principal: Lee–Yang theorem

After Onsager's solution, Yang and Lee investigated the way in which the partition function becomes singular as the temperature approaches the critical temperature.

Monte Carlo methods for numerical simulation

Quench of an Ising system on a two dimensional square lattice (500x500) with inverse temperature β = 10 starting from a random configuration.

Definitions

The Ising model can often be difficult to evaluate numerically if there are many states in the system. Consider an Ising Model with L lattice sites. Let:

• L = |Λ|: the total number of sites on the lattice,
• σ_j ∈ {−1, +1}: an individual spin site on the lattice, j = 1, ..., L,
• S ∈ {−1, +1}^L: state of the system.

Since every spin site has ±1 spin, there are 2^L different states that are possible. This motivates the reason for the Ising Model to be simulated using Monte Carlo Methods.

The Hamiltonian Function that is commonly used representing the energy of the model when using Monte Carlo Methods is:

$H(\sigma )=-J\sum _{\langle ij\rangle }\sigma _{i}\sigma _{j}-h\sum _{j}\sigma _{j}.$

Furthermore, the Hamiltonian is further simplified by assuming zero external field (h) since many questions that are posed to be solved using the model can be answered in absence of an external field. This leads us to the following energy equation for state σ:

$H(\sigma )=-J\sum _{\langle ij\rangle }\sigma _{i}\sigma _{j}.$

Two such examples of estimates of interest are the specific heat or the magnetization of the magnet at a given temperature.

The Metropolis algorithm

Overview of algorithm

The Metropolis–Hastings algorithm is the most commonly used Monte Carlo algorithm to calculate Ising Model estimations. The algorithm first chooses selection probabilities g(μ, ν), which represent the probability that state ν is selected by the algorithm out of all states, given that we are in state μ. It then uses acceptance probabilities A(μ, ν) so that detailed balance is satisfied. If the new state ν is accepted, then we move to that state and repeat with selecting a new state and deciding to accept it. If ν is not accepted then we stay in μ. This process is repeated until some stopping criteria is met, which for the Ising model is often when the lattice becomes ferromagnetic, meaning all of the sites point in the same direction.

When implementing the algorithm, we must ensure that g(μ, ν) is selected such that ergodicity is met. In thermal equilibrium a system's energy only fluctuates within a small range. This is the motivation behind the concept of single-spin-flip dynamics, which states that in each transition, we will only change one of the spin sites on the lattice. Furthermore, by using single- spin-flip dynamics, we can get from any state to any other state by flipping each site that differs between the two states one at a time.

The maximum amount of change between the energy of the present state, H_μ and any possible new state's energy H_ν (using single-spin-flip dynamics) is 2J between the spin we choose to "flip" to move to the new state and that spin's neighbor. Thus, in a 1D-Ising Model, where each site has 2 neighbors (left, and right), the maximum difference in energy would be 4J.

Let c represent the lattice coordination number; the number of nearest neighbors that any lattice site has. We assume that all sites have the same number of neighbors due to periodic boundary conditions. It is important to note that the Metropolis–Hastings algorithm does not perform well around the critical point due to critical slowing down. Other techniques such as multigrid methods, Niedermayer's algorithm, Swendsen–Wang algorithm, or the Wolff algorithm are required in order to resolve the model near the critical point; a requirement for determining the critical exponents of the system.

Algorithm specification

Specifically for the Ising model and using single-spin-flip dynamics, we can establish the following.

Since there are L total sites on the lattice, using single-spin-flip as the only way we transition to another state, we can see that there are a total of L new states ν from our present state μ. The algorithm assumes that the selection probabilities are equal to the L states: g(μ, ν) = 1/L. Detailed balance tells us that the following equation must hold:

${\frac {P(\mu ,\nu )}{P(\nu ,\mu )}}={\frac {g(\mu ,\nu )A(\mu ,\nu )}{g(\nu ,\mu )A(\nu ,\mu )}}={\frac {A(\mu ,\nu )}{A(\nu ,\mu )}}={\frac {P_{\beta }(\nu )}{P_{\beta }(\mu )}}={\frac {{\frac {1}{Z}}e^{-\beta (H_{\nu })}}{{\frac {1}{Z}}e^{-\beta (H_{\mu })}}}=e^{-\beta (H_{\nu }-H_{\mu })}.$

Thus, we want to select the acceptance probability for our algorithm to satisfy:

${\frac {A(\mu ,\nu )}{A(\nu ,\mu )}}=e^{-\beta (H_{\nu }-H_{\mu })}.$

If H_ν > H_μ then A(ν, μ) > A(μ, ν) Metropolis sets the larger of A(μ, ν) or A(ν, μ) to be 1. By this reasoning the acceptance algorithm is:

$A(\mu ,\nu )={\begin{cases}e^{-\beta (H_{\nu }-H_{\mu })},&{\text{if }}H_{\nu }-H_{\mu }>0\\1,&{\text{otherwise}}.\end{cases}}$

The basic form of the algorithm is as follows:

1. Pick a spin site using selection probability g(μ, ν) and calculate the contribution to the energy involving this spin.
2. Flip the value of the spin and calculate the new contribution.
3. If the new energy is less, keep the flipped value.
4. If the new energy is more, only keep with probability $e^{-\beta (H_{\nu }-H_{\mu })}.$
5. Repeat.

The change in energy H_ν−H_μ only depends on the value of the spin and its nearest graph neighbors. So if the graph is not too connected, the algorithm is fast. This process will eventually produce a pick from the distribution.

Viewing the Ising model as a Markov chain

It is easy to view the Ising Model as a Markov Chain, as the immediate future state ν transition probability: P_β(ν) only depends on the present state μ. The Metropolis Algorithm is actually a version of Markov Chain Monte Carlo simulation, and since we use single-spin-flip dynamics in the Metropolis Algorithm, every state can be viewed as having links to exactly L other states, where each transition corresponds to flipping a single spin site to the opposite dipole. Furthermore, since the energy equation H_σ change only depending on the nearest neighbors interaction influence 'J', we can view the Ising model and its variations such the Sznajd model as a form of Voter Model for opinion dynamics.

One dimension

The thermodynamic limit exists as soon as the interaction decay is $J_{ij}\sim |i-j|^{-\alpha }$ with α > 1.

• In the case of ferromagnetic interaction $J_{ij}\sim |i-j|^{-\alpha }$ with 1< α < 2 Dyson proved, by comparison with the hierarchical case, that there is phase transition at small enough temperature.
• In the case of ferromagnetic interaction $J_{ij}\sim |i-j|^{-2}$, Fröhlich and Spencer proved that there is phase transition at small enough temperature (in contrast with the hierarchical case).
• In the case of interaction $J_{ij}\sim |i-j|^{-\alpha }$ with α > 2 (that includes the case of finite range interactions) there is no phase transition at any positive temperature (i.e. finite β) since the free energy is analytic in the thermodynamic parameters.
• In the case of nearest neighbor interactions, E. Ising provided an exact solution of the model. At any positive temperature (i.e. finite β) the free energy is analytic in the thermodynamics parameters and the truncated two-point spin correlation decays exponentially fast. At zero temperature, (i.e. infinite β), there is a second order phase transition: the free energy is infinite and the truncated two point spin correlation does not decay (remains constant). Therefore, T = 0 is the critical temperature of this case. Scaling formulas are satisfied.

Ising's exact solution

In the nearest neighbor case (with periodic or free boundary conditions) an exact solution is available. The energy of the one-dimensional Ising model on a lattice of L sites with periodic boundary conditions is

$H(\sigma )=-J\sum _{i=1,\ldots ,L-1}\sigma _{i}\sigma _{i+1}-h\sum _{i}\sigma _{i}$

where J and h can be any number, since in this simplified case J is a constant representing the interaction strength between the nearest neighbors and h is the constant external magnetic field applied to lattice sites. Then the free energy is

$f(\beta ,h)=-\lim _{L\to \infty }{\frac {1}{\beta L}}\ln(Z(\beta ))=-{\frac {1}{\beta }}\ln \left(e^{\beta J}\cosh \beta h+{\sqrt {e^{2\beta J}(\sinh \beta h)^{2}+e^{-2\beta J}}}\right)$

and the spin-spin correlation is

$\langle \sigma _{i}\sigma _{j}\rangle -\langle \sigma _{i}\rangle \langle \sigma _{j}\rangle =C(\beta )e^{-c(\beta )|i-j|}$

where C(β) and c(β) are positive functions for T > 0. For T → 0, though, the inverse correlation length, c(β), vanishes.

Proof

The proof of this result is a simple computation.

If h = 0, it is very easy to obtain the free energy in the case of free boundary condition, i.e. when

$H(\sigma )=-J(\sigma _{1}\sigma _{2}+\cdots +\sigma _{L-1}\sigma _{L}).$

Then the model factorizes under the change of variables

$\sigma '_{j}=\sigma _{j}\sigma _{j-1}\qquad j\geq 2.$

That gives

$Z(\beta )=\sum _{\sigma _{1},\ldots ,\sigma _{L}}e^{\beta J\sigma _{1}\sigma _{2}}\;e^{\beta J\sigma _{2}\sigma _{3}}\;\cdots e^{\beta J\sigma _{L-1}\sigma _{L}}=2\prod _{j=2}^{L}\sum _{\sigma '_{j}}e^{\beta J\sigma '_{j}}=2\left[e^{\beta J}+e^{-\beta J}\right]^{L-1}.$

Therefore, the free energy is

$f(\beta ,0)=-{\frac {1}{\beta }}\ln \left[e^{\beta J}+e^{-\beta J}\right].$

With the same change of variables

$\langle \sigma _{j}\sigma _{j+N}\rangle =\left[{\frac {e^{\beta J}-e^{-\beta J}}{e^{\beta J}+e^{-\beta J}}}\right]^{N}$

hence it decays exponentially as soon as T ≠ 0; but for T = 0, i.e. in the limit β → ∞ there is no decay.

If h ≠ 0 we need the transfer matrix method. For the periodic boundary conditions case is the following. The partition function is

$Z(\beta )=\sum _{\sigma _{1},\ldots ,\sigma _{L}}e^{\beta h\sigma _{1}}e^{\beta J\sigma _{1}\sigma _{2}}\;e^{\beta h\sigma _{2}}e^{\beta J\sigma _{2}\sigma _{3}}\;\cdots e^{\beta h\sigma _{L}}e^{\beta J\sigma _{L}\sigma _{1}}=\sum _{\sigma _{1},\ldots ,\sigma _{L}}V_{\sigma _{1},\sigma _{2}}V_{\sigma _{2},\sigma _{3}}\cdots V_{\sigma _{L},\sigma _{1}}.$

The coefficients $V_{\sigma ,\sigma '}$'s can be seen as the entries of a matrix. There are different possible choices: a convenient one (because the matrix is symmetric) is

$V_{\sigma ,\sigma '}=e^{{\frac {\beta h}{2}}\sigma }e^{\beta J\sigma \sigma '}e^{{\frac {\beta h}{2}}\sigma '}$

or

$V={\begin{bmatrix}e^{\beta (h+J)}&e^{-\beta J}\\e^{-\beta J}&e^{-\beta (h-J)}\end{bmatrix}}.$

In matrix formalism

$Z(\beta )={\rm {Tr}}\left(V^{L}\right)=\lambda _{1}^{L}+\lambda _{2}^{L}=\lambda _{1}^{L}\left[1+\left({\frac {\lambda _{2}}{\lambda _{1}}}\right)^{L}\right]$

where λ₁ is the highest eigenvalue of V, while λ₂ is the other eigenvalue:

$\lambda _{1}=e^{\beta J}\cosh \beta h+{\sqrt {e^{2\beta J}(\sinh \beta h)^{2}+e^{-2\beta J}}}$

and |λ₂| < λ₁. This gives the formula of the free energy.

Comments

The energy of the lowest state is −L, when all the spins are the same. For any other configuration, the extra energy is equal to the number of sign changes as you scan the configuration from left to right.

If we designate the number of sign changes in a configuration as k, the difference in energy from the lowest energy state is 2k. Since the energy is additive in the number of flips, the probability p of having a spin-flip at each position is independent. The ratio of the probability of finding a flip to the probability of not finding one is the Boltzmann factor:

${p \over 1-p}=e^{-2\beta J}.$

The problem is reduced to independent biased coin tosses. This essentially completes the mathematical description.

From the description in terms of independent tosses, the statistics of the model for long lines can be understood. The line splits into domains. Each domain is of average length exp(2β). The length of a domain is distributed exponentially, since there is a constant probability at any step of encountering a flip. The domains never become infinite, so a long system is never magnetized. Each step reduces the correlation between a spin and its neighbor by an amount proportional to p, so the correlations fall off exponentially.

$\langle S_{i}S_{j}\rangle \,\propto \,e^{-p|i-j|}.$

The partition function is the volume of configurations, each configuration weighted by its Boltzmann weight. Since each configuration is described by the sign-changes, the Partition function factorizes:

$Z=\sum _{\mathrm {configs} }e^{\sum _{k}S_{k}}=\prod _{k}(1+p)=(1+p)^{L}.$

The logarithm divided by L is the free energy density:

$\beta f=\log(1+p)=\log \left(1+{e^{-2\beta J} \over 1+e^{-2\beta J}}\right),$

which is analytic away from β = ∞. A sign of a phase transition is a non-analytic free energy, so the one-dimensional model does not have a phase transition.

One-dimensional solution with transverse field

To express the Ising Hamiltonian using a quantum mechanical description of spins, we replace the spin variables with their respective Pauli matrices. However, depending on the direction of the magnetic field, we can create a transverse-field or longitudinal-field Hamiltonian. The transverse-field Hamiltonian is given by

$H(\sigma )=-J\sum _{i=1,\ldots ,L}\sigma _{i}^{z}\sigma _{i+1}^{z}-h\sum _{i}\sigma _{i}^{x}.$

The transverse-field model experiences a phase transition between an ordered and disordered regime at J~h. This can be shown by a mapping of Pauli matrices

$\sigma _{n}^{z}=\prod _{i=1}^{n}T_{i}^{x},$

$\sigma _{n}^{x}=T_{n}^{z}T_{n+1}^{z}.$

Upon rewriting the Hamiltonian in terms of this change-of-basis matrices, we obtain

$H(\sigma )=-h\sum _{i=1,\ldots ,L}T_{i}^{z}T_{i+1}^{z}-J\sum _{i}T_{i}^{x}.$

Since the roles of h and J are switched, the Hamiltonian undergoes a transition at J = h.

Two dimensions

• In the ferromagnetic case there is a phase transition: at low temperature, Peierls argument proves positive magnetization for the nearest neighbor case and then, by Griffiths inequality, also when longer range interactions are added; while, at high temperature, cluster expansion gives analyticity of the thermodynamic functions.
• In the nearest-neighbor case, the free energy has been exactly computed by Onsager, through the equivalence of the model with free fermions on lattice. The spin-spin correlation functions has been computed by McCoy and Wu.

Onsager's exact solution

Ver artigo principal: square-lattice Ising model

Onsager obtained the following analytical expression for the free energy of the Ising model on the anisotropic square lattice when the magnetic field $h=0$ in the thermodynamic limit as a function of temperature and the horizontal and vertical interaction energies $J_{1}$ and $J_{2}$, respectively

$-\beta f=\ln 2+{\frac {1}{8\pi ^{2}}}\int _{0}^{2\pi }d\theta _{1}\int _{0}^{2\pi }d\theta _{2}\ln[\cosh(2\beta J_{1})\cosh(2\beta J_{2})-\sinh(2\beta J_{1})\cos(\theta _{1})-\sinh(2\beta J_{2})\cos(\theta _{2})].$

From this expression for the free energy, all thermodynamic functions of the model can be calculated by using an appropriate derivative. The 2D Ising model was the first model to exhibit a continuous phase transition at a positive temperature. It occurs as the temperature $T_{c}$ which is a solution of the following equation

$\sinh \left({\frac {2J_{1}}{kT_{c}}}\right)\sinh \left({\frac {2J_{2}}{kT_{c}}}\right)=1$

In the isotropic case when the horizontal and vertical interaction energies are equal $J_{1}=J_{2}=J$, the critical temperature $T_{c}$ occurs at the following point

$T_{c}={\frac {2J}{k\ln(1+{\sqrt {2}})}}$

When the interaction energies $J_{1}$, $J_{2}$ are both negative, the Ising model becomes an antiferromagnet. Since the square lattice is bi-partite, it is invariant under this change when the magnetic field $h=0$, so the free energy and critical temperature are the same for the antiferromagnetic case. For the triangular lattice, which is not bi-partite, the ferromagnetic and antiferromagnetic Ising model behave notably differently.

Transfer matrix

Start with an analogy with quantum mechanics. The Ising model on a long periodic lattice has a partition function

$\sum _{S}\exp {\biggl (}\sum _{ij}S_{i,j}S_{i,j+1}+S_{i,j}S_{i+1,j}{\biggr )}.$

Think of the i direction as space, and the j direction as time. This is an independent sum over all the values that the spins can take at each time slice. This is a type of path integral, it is the sum over all spin histories.

A path integral can be rewritten as a Hamiltonian evolution. The Hamiltonian steps through time by performing a unitary rotation between time t and time t + Δt:

$U=e^{iH\Delta t}$

The product of the U matrices, one after the other, is the total time evolution operator, which is the path integral we started with.

$U^{N}=(e^{iH\Delta t})^{N}=\int DXe^{iL}$

where N is the number of time slices. The sum over all paths is given by a product of matrices, each matrix element is the transition probability from one slice to the next.

Similarly, one can divide the sum over all partition function configurations into slices, where each slice is the one-dimensional configuration at time 1. This defines the transfer matrix:

$T_{C_{1}C_{2}}.$

The configuration in each slice is a one-dimensional collection of spins. At each time slice, T has matrix elements between two configurations of spins, one in the immediate future and one in the immediate past. These two configurations are C₁ and C₂, and they are all one-dimensional spin configurations. We can think of the vector space that T acts on as all complex linear combinations of these. Using quantum mechanical notation:

$|A\rangle =\sum _{S}A(S)|S\rangle$

where each basis vector $|S\rangle$ is a spin configuration of a one-dimensional Ising model.

Like the Hamiltonian, the transfer matrix acts on all linear combinations of states. The partition function is a matrix function of T, which is defined by the sum over all histories which come back to the original configuration after N steps:

$Z=\mathrm {tr} (T^{N}).$

Since this is a matrix equation, it can be evaluated in any basis. So if we can diagonalize the matrix T, we can find Z.

T in terms of Pauli matrices

The contribution to the partition function for each past/future pair of configurations on a slice is the sum of two terms. There is the number of spin flips in the past slice and there is the number of spin flips between the past and future slice. Define an operator on configurations which flips the spin at site i:

$\sigma _{i}^{x}.$

In the usual Ising basis, acting on any linear combination of past configurations, it produces the same linear combination but with the spin at position i of each basis vector flipped.

Define a second operator which multiplies the basis vector by +1 and −1 according to the spin at position i:

$\sigma _{i}^{z}.$

T can be written in terms of these:

$\sum _{i}A\sigma _{i}^{x}+B\sigma _{i}^{z}\sigma _{i+1}^{z}$

where A and B are constants which are to be determined so as to reproduce the partition function. The interpretation is that the statistical configuration at this slice contributes according to both the number of spin flips in the slice, and whether or not the spin at position i' has flipped.

Spin flip creation and annihilation operators

Just as in the one-dimensional case, we will shift attention from the spins to the spin-flips. The σ^z term in T counts the number of spin flips, which we can write in terms of spin-flip creation and annihilation operators:

$\sum C\psi _{i}^{\dagger }\psi _{i}.\,$

The first term flips a spin, so depending on the basis state it either:

1. moves a spin-flip one unit to the right
2. moves a spin-flip one unit to the left
3. produces two spin-flips on neighboring sites
4. destroys two spin-flips on neighboring sites.

Writing this out in terms of creation and annihilation operators:

$\sigma _{i}^{x}=D{\psi ^{\dagger }}_{i}\psi _{i+1}+D^{*}{\psi ^{\dagger }}_{i}\psi _{i-1}+C\psi _{i}\psi _{i+1}+C^{*}{\psi ^{\dagger }}_{i}{\psi ^{\dagger }}_{i+1}.$

Ignore the constant coefficients, and focus attention on the form. They are all quadratic. Since the coefficients are constant, this means that the T matrix can be diagonalized by Fourier transforms.

Carrying out the diagonalization produces the Onsager free energy.

Onsager's formula for spontaneous magnetization

Onsager famously announced the following expression for the spontaneous magnetization M of a two-dimensional Ising ferromagnet on the square lattice at two different conferences in 1948, though without proof

$M=\left(1-\left[\sinh 2\beta J_{1}\sinh 2\beta J_{2}\right]^{-2}\right)^{\frac {1}{8}}$

where $J_{1}$ and $J_{2}$ are horizontal and vertical interaction energies.

A complete derivation was only given in 1951 by Yang (1952) using a limiting process of transfer matrix eigenvalues. The proof was subsequently greatly simplified in 1963 by Montroll, Potts, and Ward using Szegő's limit formula for Toeplitz determinants by treating the magnetization as the limit of correlation functions.

Three and four dimensions

In three dimensions, the Ising model was shown to have a representation in terms of non-interacting Fermionic lattice strings by Alexander Polyakov. The critical point of the three-dimensional Ising model is described by a conformal field theory, as evidenced by Monte-Carlo simulations and theoretical arguments. This conformal field theory is under active investigation using the method of the conformal bootstrap. This method currently yields the most precise information about the structure of the critical theory (see Ising critical exponents).

In dimensions near four, the critical behavior of the model is understood to correspond to the renormalization behavior of the scalar phi-4 theory (see Kenneth Wilson).

More than four dimensions

In any dimension, the Ising model can be productively described by a locally varying mean field. The field is defined as the average spin value over a large region, but not so large so as to include the entire system. The field still has slow variations from point to point, as the averaging volume moves. These fluctuations in the field are described by a continuum field theory in the infinite system limit.

Local field

The field H is defined as the long wavelength Fourier components of the spin variable, in the limit that the wavelengths are long. There are many ways to take the long wavelength average, depending on the details of how high wavelengths are cut off. The details are not too important, since the goal is to find the statistics of H and not the spins. Once the correlations in H are known, the long-distance correlations between the spins will be proportional to the long-distance correlations in H.

For any value of the slowly varying field H, the free energy (log-probability) is a local analytic function of H and its gradients. The free energy F(H) is defined to be the sum over all Ising configurations which are consistent with the long wavelength field. Since H is a coarse description, there are many Ising configurations consistent with each value of H, so long as not too much exactness is required for the match.

Since the allowed range of values of the spin in any region only depends on the values of H within one averaging volume from that region, the free energy contribution from each region only depends on the value of H there and in the neighboring regions. So F is a sum over all regions of a local contribution, which only depends on H and its derivatives.

By symmetry in H, only even powers contribute. By reflection symmetry on a square lattice, only even powers of gradients contribute. Writing out the first few terms in the free energy:

$\beta F=\int d^{d}x\left[AH^{2}+\sum _{i=1}^{d}Z_{i}(\partial _{i}H)^{2}+\lambda H^{4}+\cdots \right].$

On a square lattice, symmetries guarantee that the coefficients Z_i of the derivative terms are all equal. But even for an anisotropic Ising model, where the Z's in different directions are different, the fluctuations in H are isotropic in a coordinate system where the different directions of space are rescaled.

On any lattice, the derivative term

$Z_{ij}\partial _{i}H\partial _{j}H$

is a positive definite quadratic form, and can be used to define the metric for space. So any translationally invariant Ising model is rotationally invariant at long distances, in coordinates that make Z_ij = δ_ij. Rotational symmetry emerges spontaneously at large distances just because there aren't very many low order terms. At higher order multicritical points, this accidental symmetry is lost.

Since βF is a function of a slowly spatially varying field. The probability of any field configuration is:

$P(H)\propto e^{-\int d^{d}x\left[AH^{2}+Z|\nabla H|^{2}+\lambda H^{4}\right]}.$

The statistical average of any product of H's is equal to:

$\langle H(x_{1})H(x_{2})\cdots H(x_{n})\rangle ={\int DHP(H)H(x_{1})H(x_{2})\cdots H(x_{n}) \over \int DHP(H)}.$

The denominator in this expression is called the partition function, and the integral over all possible values of H is a statistical path integral. It integrates exp(βF) over all values of H, over all the long wavelength fourier components of the spins. F is a Euclidean Lagrangian for the field H, the only difference between this and the quantum field theory of a scalar field is that all the derivative terms enter with a positive sign, and there is no overall factor of i.

$Z=\int DHe^{\int d^{d}x\left[AH^{2}+Z|\nabla H|^{2}+\lambda H^{4}\right]}$

Dimensional analysis

The form of F can be used to predict which terms are most important by dimensional analysis. Dimensional analysis is not completely straightforward, because the scaling of H needs to be determined.

In the generic case, choosing the scaling law for H is easy, the only term that contributes is the first one,

$F=\int d^{d}xAH^{2}.$

This term is the most significant, but it gives trivial behavior. This form of the free energy is ultralocal, meaning that it is a sum of an independent contribution from each point. This is like the spin-flips in the one-dimensional Ising model. Every value of H at any point fluctuates completely independently of the value at any other point.

The scale of the field can be redefined to absorb the coefficient A, and then it is clear that A only determines the overall scale of fluctuations. The ultralocal model describes the long wavelength high temperature behavior of the Ising model, since in this limit the fluctuation averages are independent from point to point.

To find the critical point, lower the temperature. As the temperature goes down, the fluctuations in H go up because the fluctuations are more correlated. This means that the average of a large number of spins does not become small as quickly as if they were uncorrelated, because they tend to be the same. This corresponds to decreasing A in the system of units where H does not absorb A. The phase transition can only happen when the subleading terms in F can contribute, but since the first term dominates at long distances, the coefficient A must be tuned to zero. This is the location of the critical point:

$F=\int d^{d}x\left[tH^{2}+\lambda H^{4}+Z(\nabla H)^{2}\right],$

where t is a parameter which goes through zero at the transition.

Since t is vanishing, fixing the scale of the field using this term makes the other terms blow up. Once t is small, the scale of the field can either be set to fix the coefficient of the H⁴ term or the (∇H)² term to 1.

Magnetization

To find the magnetization, fix the scaling of H so that λ is one. Now the field H has dimension −d/4, so that H⁴d^dx is dimensionless, and Z has dimension 2 − d/2. In this scaling, the gradient term is only important at long distances for d ≤ 4. Above four dimensions, at long wavelengths, the overall magnetization is only affected by the ultralocal terms.

There is one subtle point. The field H is fluctuating statistically, and the fluctuations can shift the zero point of t. To see how, consider H⁴ split in the following way:

$H(x)^{4}=-\langle H(x)^{2}\rangle ^{2}+2\langle H(x)^{2}\rangle H(x)^{2}+\left(H(x)^{2}-\langle H(x)^{2}\rangle \right)^{2}$

The first term is a constant contribution to the free energy, and can be ignored. The second term is a finite shift in t. The third term is a quantity that scales to zero at long distances. This means that when analyzing the scaling of t by dimensional analysis, it is the shifted t that is important. This was historically very confusing, because the shift in t at any finite λ is finite, but near the transition t is very small. The fractional change in t is very large, and in units where t is fixed the shift looks infinite.

The magnetization is at the minimum of the free energy, and this is an analytic equation. In terms of the shifted t,

${\partial \over \partial H}\left(tH^{2}+\lambda H^{4}\right)=2tH+4\lambda H^{3}=0$

For t < 0, the minima are at H proportional to the square root of t. So Landau's catastrophe argument is correct in dimensions larger than 5. The magnetization exponent in dimensions higher than 5 is equal to the mean field value.

When t is negative, the fluctuations about the new minimum are described by a new positive quadratic coefficient. Since this term always dominates, at temperatures below the transition the flucuations again become ultralocal at long distances.

Fluctuations

To find the behavior of fluctuations, rescale the field to fix the gradient term. Then the length scaling dimension of the field is 1 − d/2. Now the field has constant quadratic spatial fluctuations at all temperatures. The scale dimension of the H² term is 2, while the scale dimension of the H⁴ term is 4 − d. For d < 4, the H⁴ term has positive scale dimension. In dimensions higher than 4 it has negative scale dimensions.

This is an essential difference. In dimensions higher than 4, fixing the scale of the gradient term means that the coefficient of the H⁴ term is less and less important at longer and longer wavelengths. The dimension at which nonquadratic contributions begin to contribute is known as the critical dimension. In the Ising model, the critical dimension is 4.

In dimensions above 4, the critical fluctuations are described by a purely quadratic free energy at long wavelengths. This means that the correlation functions are all computable from as Gaussian averages:

$\langle S(x)S(y)\rangle \propto \langle H(x)H(y)\rangle =G(x-y)=\int {dk \over (2\pi )^{d}}{e^{ik(x-y)} \over k^{2}+t}$

valid when x − y is large. The function G(x − y) is the analytic continuation to imaginary time of the Feynman propagator, since the free energy is the analytic continuation of the quantum field action for a free scalar field. For dimensions 5 and higher, all the other correlation functions at long distances are then determined by Wick's theorem. All the odd moments are zero, by ± symmetry. The even moments are the sum over all partition into pairs of the product of G(x − y) for each pair.

$\langle S(x_{1})S(x_{2})\cdots S(x_{2n})\rangle =C^{n}\sum G(x_{i1},x_{j1})G(x_{i2},X_{j2})\ldots G(x_{in},x_{jn})$

where C is the proportionality constant. So knowing G is enough. It determines all the multipoint correlations of the field.

The critical two-point function

To determine the form of G, consider that the fields in a path integral obey the classical equations of motion derived by varying the free energy:

${\begin{aligned}&&\left(-\nabla _{x}^{2}+t\right)\langle H(x)H(y)\rangle &=0\\\rightarrow {}&&\nabla ^{2}G(x)+tG(x)&=0\end{aligned}}$

This is valid at noncoincident points only, since the correlations of H are singular when points collide. H obeys classical equations of motion for the same reason that quantum mechanical operators obey them—its fluctuations are defined by a path integral.

At the critical point t = 0, this is Laplace's equation, which can be solved by Gauss's method from electrostatics. Define an electric field analog by

$E=\nabla G$

away from the origin:

$\nabla \cdot E=0$

since G is spherically symmetric in d dimensions, E is the radial gradient of G. Integrating over a large d − 1 dimensional sphere,

$\int d^{d-1}SE_{r}=\mathrm {constant}$

This gives:

$E={C \over r^{d-1}}$

and G can be found by integrating with respect to r.

$G(r)={C \over r^{d-2}}$

The constant C fixes the overall normalization of the field.

G(r) away from the critical point

When t does not equal zero, so that H is fluctuating at a temperature slightly away from critical, the two point function decays at long distances. The equation it obeys is altered:

$\nabla ^{2}G+tG=0\to {1 \over r^{d-1}}{d \over dr}\left(r^{d-1}{dG \over dr}\right)+tG(r)=0$

For r small compared with ${\sqrt {t}}$, the solution diverges exactly the same way as in the critical case, but the long distance behavior is modified.

To see how, it is convenient to represent the two point function as an integral, introduced by Schwinger in the quantum field theory context:

$G(x)=\int d\tau {1 \over \left({\sqrt {2\pi \tau }}\right)^{d}}e^{-{x^{2} \over 4\tau }-t\tau }$

This is G, since the Fourier transform of this integral is easy. Each fixed τ contribution is a Gaussian in x, whose Fourier transform is another Gaussian of reciprocal width in k.

$G(k)=\int d\tau e^{-(k^{2}-t)\tau }={1 \over k^{2}-t}$

This is the inverse of the operator ∇² − t in k space, acting on the unit function in k space, which is the Fourier transform of a delta function source localized at the origin. So it satisfies the same equation as G with the same boundary conditions that determine the strength of the divergence at 0.

The interpretation of the integral representation over the proper time τ is that the two point function is the sum over all random walk paths that link position 0 to position x over time τ. The density of these paths at time τ at position x is Gaussian, but the random walkers disappear at a steady rate proportional to t so that the Gaussian at time τ is diminished in height by a factor that decreases steadily exponentially. In the quantum field theory context, these are the paths of relativistically localized quanta in a formalism that follows the paths of individual particles. In the pure statistical context, these paths still appear by the mathematical correspondence with quantum fields, but their interpretation is less directly physical.

The integral representation immediately shows that G(r) is positive, since it is represented as a weighted sum of positive Gaussians. It also gives the rate of decay at large r, since the proper time for a random walk to reach position τ is r² and in this time, the Gaussian height has decayed by $e^{-t\tau }=e^{-tr^{2}}$. The decay factor appropriate for position r is therefore $e^{-{\sqrt {t}}r}$.

A heuristic approximation for G(r) is:

$G(r)\approx {e^{-{\sqrt {t}}r} \over r^{d-2}}$

This is not an exact form, except in three dimensions, where interactions between paths become important. The exact forms in high dimensions are variants of Bessel functions.

Symanzik polymer interpretation

The interpretation of the correlations as fixed size quanta travelling along random walks gives a way of understanding why the critical dimension of the H⁴ interaction is 4. The term H⁴ can be thought of as the square of the density of the random walkers at any point. In order for such a term to alter the finite order correlation functions, which only introduce a few new random walks into the fluctuating environment, the new paths must intersect. Otherwise, the square of the density is just proportional to the density and only shifts the H² coefficient by a constant. But the intersection probability of random walks depends on the dimension, and random walks in dimension higher than 4 don't intersect.

The fractal dimension of an ordinary random walk is 2. The number of balls of size ε required to cover the path increase as ε⁻². Two objects of fractal dimension 2 will intersect with reasonable probability only in a space of dimension 4 or less, the same condition as for a generic pair of planes. Kurt Symanzik argued that this implies that the critical Ising fluctuations in dimensions higher than 4 should be described by a free field. This argument eventually became a mathematical proof.

4 − ε dimensions – renormalization group

The Ising model in four dimensions is described by a fluctuating field, but now the fluctuations are interacting. In the polymer representation, intersections of random walks are marginally possible. In the quantum field continuation, the quanta interact.

The negative logarithm of the probability of any field configuration H is the free energy function

$F=\int d^{4}x\left[{Z \over 2}|\nabla H|^{2}+{t \over 2}H^{2}+{\lambda \over 4!}H^{4}\right]\,$

The numerical factors are there to simplify the equations of motion. The goal is to understand the statistical fluctuations. Like any other non-quadratic path integral, the correlation functions have a Feynman expansion as particles travelling along random walks, splitting and rejoining at vertices. The interaction strength is parametrized by the classically dimensionless quantity λ.

Although dimensional analysis shows that both λ and Z dimensionless, this is misleading. The long wavelength statistical fluctuations are not exactly scale invariant, and only become scale invariant when the interaction strength vanishes.

The reason is that there is a cutoff used to define H, and the cutoff defines the shortest wavelength. Fluctuations of H at wavelengths near the cutoff can affect the longer-wavelength fluctuations. If the system is scaled along with the cutoff, the parameters will scale by dimensional analysis, but then comparing parameters doesn't compare behavior because the rescaled system has more modes. If the system is rescaled in such a way that the short wavelength cutoff remains fixed, the long-wavelength fluctuations are modified.

Wilson renormalization

A quick heuristic way of studying the scaling is to cut off the H wavenumbers at a point λ. Fourier modes of H with wavenumbers larger than λ are not allowed to fluctuate. A rescaling of length that make the whole system smaller increases all wavenumbers, and moves some fluctuations above the cutoff.

To restore the old cutoff, perform a partial integration over all the wavenumbers which used to be forbidden, but are now fluctuating. In Feynman diagrams, integrating over a fluctuating mode at wavenumber k links up lines carrying momentum k in a correlation function in pairs, with a factor of the inverse propagator.

Under rescaling, when the system is shrunk by a factor of (1+b), the t coefficient scales up by a factor (1+b)² by dimensional analysis. The change in t for infinitesimal b is 2bt. The other two coefficients are dimensionless and don't change at all.

The lowest order effect of integrating out can be calculated from the equations of motion:

$\nabla ^{2}H+tH=-{\lambda \over 6}H^{3}.$

This equation is an identity inside any correlation function away from other insertions. After integrating out the modes with Λ < k < (1+b)Λ, it will be a slightly different identity.

Since the form of the equation will be preserved, to find the change in coefficients it is sufficient to analyze the change in the H³ term. In a Feynman diagram expansion, the H³ term in a correlation function inside a correlation has three dangling lines. Joining two of them at large wavenumber k gives a change H³ with one dangling line, so proportional to H:

$\delta H^{3}=3H\int _{\Lambda <|k|<(1+b)\Lambda }{d^{4}k \over (2\pi )^{4}}{1 \over (k^{2}+t)}$

The factor of 3 comes from the fact that the loop can be closed in three different ways.

The integral should be split into two parts:

$\int dk{1 \over k^{2}}-t\int dk{1 \over k^{2}(k^{2}+t)}=A\Lambda ^{2}b+Bbt$

the first part is not proportional to t, and in the equation of motion it can be absorbed by a constant shift in t. It is caused by the fact that the H³ term has a linear part. part is independent of the value of t. Only the second term, which varies from t to t, contributes to the critical scaling.

This new linear term adds to the first term on the left hand side, changing t by an amount proportional to t. The total change in t is the sum of the term from dimensional analysis and this second term from operator products:

$\delta t=\left(2-{B\lambda \over 2}\right)bt$

So t is rescaled, but its dimension is anomalous, it is changed by an amount proportional to the value of λ.

But λ also changes. The change in lambda requires considering the lines splitting and then quickly rejoining. The lowest order process is one where one of the three lines from H³ splits into three, which quickly joins with one of the other lines from the same vertex. The correction to the vertex is

$\delta \lambda =-{3\lambda ^{2} \over 2}\int _{k}dk{1 \over (k^{2}+t)^{2}}=-{3\lambda ^{2} \over 2}b$

The numerical factor is three times bigger because there is an extra factor of three in choosing which of the three new lines to contract. So

$\delta \lambda =-3B\lambda ^{2}b$

These two equations together define the renormalization group equations in four dimensions:

${\begin{aligned}{dt \over t}&=\left(2-{B\lambda \over 2}\right)b\\{d\lambda \over \lambda }&={-3B\lambda \over 2}b\end{aligned}}$

The coefficient B is determined by the formula

$Bb=\int _{\Lambda <|k|<(1+b)\Lambda }{d^{4}k \over (2\pi )^{4}}{1 \over k^{4}}$

And is proportional to the area of a three-dimensional sphere of radius λ, times the width of the integration region bΛ divided by Λ⁴

$B=(2\pi ^{2}\Lambda ^{3}){1 \over (2\pi )^{4}}{b\Lambda }{1 \over b\Lambda ^{4}}={1 \over 8\pi ^{2}}$

In other dimensions, the constant B changes, but the same constant appears both in the t flow and in the coupling flow. The reason is that the derivative with respect to t of the closed loop with a single vertex is a closed loop with two vertices. This means that the only difference between the scaling of the coupling and the t is the combinatorial factors from joining and splitting.

Wilson–Fisher point

To investigate three dimensions starting from the four-dimensional theory should be possible, because the intersection probabilities of random walks depend continuously on the dimensionality of the space. In the language of Feynman graphs, the coupling doesn't change very much when the dimension is changed.

The process of continuing away from dimension four is not completely well defined without a prescription for how to do it. The prescription is only well defined on diagrams. It replaces the Schwinger representation in dimension 4 with the Schwinger representation in dimension 4 − ε defined by:

$G(x-y)=\int d\tau {1 \over t^{d \over 2}}e^{{x^{2} \over 2\tau }+t\tau }$

In dimension 4 − ε, the coupling λ has positive scale dimension ε, and this must be added to the flow.

${\begin{aligned}{d\lambda \over \lambda }&=\varepsilon -3B\lambda \\{dt \over t}&=2-\lambda B\end{aligned}}$

The coefficient B is dimension dependent, but it will cancel. The fixed point for λ is no longer zero, but at:

$\lambda ={\varepsilon \over 3B}$

where the scale dimensions of t is altered by an amount λB = ε/3.

The magnetization exponent is altered proportionately to:

${\tfrac {1}{2}}\left(1-{\varepsilon \over 3}\right)$

which is .333 in 3 dimensions (ε = 1) and .166 in 2 dimensions (ε = 2). This is not so far off from the measured exponent .308 and the Onsager two dimensional exponent .125.

Infinite dimensions – mean field

Ver artigo principal: Mean field theory

The behavior of an Ising model on a fully connected graph may be completely understood by mean field theory. This type of description is appropriate to very-high-dimensional square lattices, because then each site has a very large number of neighbors.

The idea is that if each spin is connected to a large number of spins, only the average number of + spins to − spins is important, since the fluctuations about this mean will be small. The mean field H is the average fraction of spins which are + minus the average fraction of spins which are −. The energy cost of flipping a single spin in the mean field H is ±2JNH. It is convenient to redefine J to absorb the factor N, so that the limit N → ∞ is smooth. In terms of the new J, the energy cost for flipping a spin is ±2JH.

This energy cost gives the ratio of probability p that the spin is + to the probability 1−p that the spin is −. This ratio is the Boltzmann factor.

${p \over 1-p}=e^{2\beta JH}$

so that

$p={1 \over 1+e^{-2\beta JH}}$

The mean value of the spin is given by averaging 1 and −1 with the weights p and 1 − p, so the mean value is 2p − 1. But this average is the same for all spins, and is therefore equal to H.

$H=2p-1={1-e^{-2\beta JH} \over 1+e^{-2\beta JH}}=\tanh(\beta JH)$

The solutions to this equation are the possible consistent mean fields. For βJ < 1 there is only the one solution at H = 0. For bigger values of β there are three solutions, and the solution at H = 0 is unstable.

The instability means that increasing the mean field above zero a little bit produces a statistical fraction of spins which are + which is bigger than the value of the mean field. So a mean field which fluctuates above zero will produce an even greater mean field, and will eventually settle at the stable solution. This means that for temperatures below the critical value βJ = 1 the mean field Ising model undergoes a phase transition in the limit of large N.

Above the critical temperature, fluctuations in H are damped because the mean field restores the fluctuation to zero field. Below the critical temperature, the mean field is driven to a new equilibrium value, which is either the positive H or negative H solution to the equation.

For βJ = 1 + ε, just below the critical temperature, the value of H can be calculated from the Taylor expansion of the Hyperbolic tangent:

$H=\tanh(\beta JH)=(1+\varepsilon )H-{(1+\varepsilon )^{3}H^{3} \over 3}$

dividing by H to discard the unstable solution at H = 0, the stable solutions are:

$H={\sqrt {3\varepsilon }}$

The spontaneous magnetization H grows near the critical point as the square root of the change in temperature. This is true whenever H can be calculated from the solution of an analytic equation which is symmetric between positive and negative values, which led Landau to suspect that all Ising type phase transitions in all dimensions should follow this law.

The mean field exponent is universal because changes in the character of solutions of analytic equations are always described by catastrophes in the Taylor series, which is a polynomial equation. By symmetry, the equation for H must only have odd powers of H on the right hand side. Changing β should only smoothly change the coefficients. The transition happens when the coefficient of H on the right hand side is 1. Near the transition:

$H={\partial (\beta F) \over \partial h}=(1+A\varepsilon )H+BH^{3}+\cdots$

Whatever A and B are, so long as neither of them is tuned to zero, the sponetaneous magnetization will grow as the square root of ε. This argument can only fail if the free energy βF is either non-analytic or non-generic at the exact β where the transition occurs.

But the spontaneous magnetization in magnetic systems and the density in gasses near the critical point are measured very accurately. The density and the magnetization in three dimensions have the same power-law dependence on the temperature near the critical point, but the behavior from experiments is:

$H\propto \varepsilon ^{0.308}$

The exponent is also universal, it is the same in the Ising model as in the experimental magnet and gas, but it is not equal to the mean field value. This was a great surprise.

This is also true in two dimensions, where

$H\propto \varepsilon ^{0.125}$

But there it was not a surprise, because it was predicted by Onsager.

Low dimensions – block spins

In three dimensions, the perturbative series from the field theory is an expansion in a coupling constant λ which is not particularly small. The effective size of the coupling at the fixed point is one over the branching factor of the particle paths, so the expansion parameter is about 1/3. In two dimensions, the perturbative expansion parameter is 2/3.

But renormalization can also be productively applied to the spins directly, without passing to an average field. Historically, this approach is due to Leo Kadanoff and predated the perturbative ε expansion.

The idea is to integrate out lattice spins iteratively, generating a flow in couplings. But now the couplings are lattice energy coefficients. The fact that a continuum description exists guarantees that this iteration will converge to a fixed point when the temperature is tuned to criticality.

Migdal–Kadanoff renormalization

Write the two-dimensional Ising model with an infinite number of possible higher order interactions. To keep spin reflection symmetry, only even powers contribute:

$E=\sum _{ij}J_{ij}S_{i}S_{j}+\sum J_{ijkl}S_{i}S_{j}S_{k}S_{l}\ldots .$

By translation invariance,J_ij is only a function of i-j. By the accidental rotational symmetry, at large i and j its size only depends on the magnitude of the two-dimensional vector i − j. The higher order coefficients are also similarly restricted.

The renormalization iteration divides the lattice into two parts – even spins and odd spins. The odd spins live on the odd-checkerboard lattice positions, and the even ones on the even-checkerboard. When the spins are indexed by the position (i,j), the odd sites are those with i + j odd and the even sites those with i + j even, and even sites are only connected to odd sites.

The two possible values of the odd spins will be integrated out, by summing over both possible values. This will produce a new free energy function for the remaining even spins, with new adjusted couplings. The even spins are again in a lattice, with axes tilted at 45 degrees to the old ones. Unrotating the system restores the old configuration, but with new parameters. These parameters describe the interaction between spins at distances $\scriptstyle {\sqrt {2}}$ larger.

Starting from the Ising model and repeating this iteration eventually changes all the couplings. When the temperature is higher than critical, the couplings will converge to zero, since the spins at large distances are uncorrelated. But when the temperature is critical, there will be nonzero coefficients linking spins at all orders. The flow can be approximated by only considering the first few terms. This truncated flow will produce better and better approximations to the critical exponents when more terms are included.

The simplest approximation is to keep only the usual J term, and discard everything else. This will generate a flow in J, analogous to the flow in t at the fixed point of λ in the ε expansion.

To find the change in J, consider the four neighbors of an odd site. These are the only spins which interact with it. The multiplicative contribution to the partition function from the sum over the two values of the spin at the odd site is:

$e^{J(N_{+}-N_{-})}+e^{J(N_{-}-N_{+})}=2\cosh(J[N_{+}-N_{-}])$

where N_± is the number of neighbors which are ±. Ignoring the factor of 2, the free energy contribution from this odd site is:

$F=\log(\cosh[J(N_{+}-N_{-})]).$

This includes nearest neighbor and next-nearest neighbor interactions, as expected, but also a four-spin interaction which is to be discarded. To truncate to nearest neighbor interactions, consider that the difference in energy between all spins the same and equal numbers + and – is:

$\Delta F=\ln(\cosh[4J]).$

Where D is the dimension of the lattice, D is three. From nearest neighbor couplings, the difference in energy between all spins equal and staggered spins is 8J. The difference in energy between all spins equal and nonstaggered but net zero spin is 4J. Ignoring four-spin interactions, a reasonable truncation is the average of these two energies or 6J. Since each link will contribute to two odd spins, the right value to compare with the previous one is half that:

$3J'=\ln(\cosh[4J]).$

For small J, this quickly flows to zero coupling. Large J's flow to large couplings. The magnetization exponent is determined from the slope of the equation at the fixed point.

Variants of this method produce good numerical approximations for the critical exponents when many terms are included, in two and three dimensions.

Applications

Magnetism

The original motivation for the model was the phenomenon of ferromagnetism. Iron is magnetic; once it is magnetized it stays magnetized for a long time compared to any atomic time.

In the 19th century, it was thought that magnetic fields are due to currents in matter, and Ampère postulated that permanent magnets are caused by permanent atomic currents. The motion of classical charged particles could not explain permanent currents though, as shown by Larmor. In order to have ferromagnetism, the atoms must have permanent magnetic moments which are not due to the motion of classical charges.

Once the electron's spin was discovered, it was clear that the magnetism should be due to a large number of electrons spinning in the same direction. It was natural to ask how the electrons all know which direction to spin, because the electrons on one side of a magnet don't directly interact with the electrons on the other side. They can only influence their neighbors. The Ising model was designed to investigate whether a large fraction of the electrons could be made to spin in the same direction using only local forces.

Lattice gas

The Ising model can be reinterpreted as a statistical model for the motion of atoms. Since the kinetic energy doesn't depend on the position only on the momentum, the statistics of the positions only depends on the potential energy, the thermodynamics of the gas only depends on the potential energy for each configuration of atoms.

A coarse model is to make space-time a lattice and imagine that each position either contains an atom or it doesn't. The space of configuration is that of independent bits B_i, where each bit is either 0 or 1 depending on whether the position is occupied or not. An attractive interaction reduces the energy of two nearby atoms. If the attraction is only between nearest neighbors, the energy is reduced by −4JB_iB_j for each occupied neighboring pair.

The density of the atoms can be controlled by adding a chemical potential, which is a multiplicative probability cost for adding one more atom. A multiplicative factor in probability can be reinterpreted as an additive term in the logarithm – the energy. The extra energy of a configuration with N atoms is changed by μN. The probability cost of one more atom is a factor of exp(−βμ).

So the energy of the lattice gas is:

$E=-{\frac {1}{2}}\sum _{\langle i,j\rangle }4JB_{i}B_{j}+\sum _{i}\mu B_{i}$

Rewriting the bits in terms of spins, $B_{i}=(S_{i}+1)/2.$

$E=-{\frac {1}{2}}\sum _{\langle i,j\rangle }JS_{i}S_{j}-{\frac {1}{2}}\sum _{i}(4J-\mu )S_{i}$

For lattices where every site has an equal number of neighbors, this is the Ising model with a magnetic field h = (zJ − μ)/2, where z is the number of neighbors.

In biological systems, modified versions of the lattice gas model have been used to understand a range of binding behaviors. These include the binding of ligands to receptors in the cell surface, the binding of chemotaxis proteins to the flagellar motor, and the condensation of DNA.

Application to neuroscience

The activity of neurons in the brain can be modelled statistically. Each neuron at any time is either active + or inactive −. The active neurons are those that send an action potential down the axon in any given time window, and the inactive ones are those that do not. Because the neural activity at any one time is modelled by independent bits, Hopfield suggested that a dynamical Ising model would provide a first approximation to a neural network which is capable of learning.

Following the general approach of Jaynes, a recent interpretation of Schneidman, Berry, Segev and Bialek, is that the Ising model is useful for any model of neural function, because a statistical model for neural activity should be chosen using the principle of maximum entropy. Given a collection of neurons, a statistical model which can reproduce the average firing rate for each neuron introduces a Lagrange multiplier for each neuron:

$E=-\sum _{i}h_{i}S_{i}$

But the activity of each neuron in this model is statistically independent. To allow for pair correlations, when one neuron tends to fire (or not to fire) along with another, introduce pair-wise lagrange multipliers:

$E=-{\tfrac {1}{2}}\sum _{ij}J_{ij}S_{i}S_{j}-\sum _{i}h_{i}S_{i}$

where $J_{ij}$ are not restricted to neighbors. Note that this generalization of Ising model is sometimes called the quadratic exponential binary distribution in statistics. This energy function only introduces probability biases for a spin having a value and for a pair of spins having the same value. Higher order correlations are unconstrained by the multipliers. An activity pattern sampled from this distribution requires the largest number of bits to store in a computer, in the most efficient coding scheme imaginable, as compared with any other distribution with the same average activity and pairwise correlations. This means that Ising models are relevant to any system which is described by bits which are as random as possible, with constraints on the pairwise correlations and the average number of 1s, which frequently occurs in both the physical and social sciences.

Spin glasses

With the Ising model the so-called spin glasses can also be described, by the usual Hamiltonian ${\hat {H}}=-{\frac {1}{2}}\,\sum J_{i,k}\,S_{i}\,S_{k},$ where the S-variables describe the Ising spins, while the J_i,k are taken from a random distribution. For spin glasses a typical distribution chooses antiferromagnetic bonds with probability p and ferromagnetic bonds with probability 1 − p. These bonds stay fixed or "quenched" even in the presence of thermal fluctuations. When p = 0 we have the original Ising model. This system deserves interest in its own; particularly one has "non-ergodic" properties leading to strange relaxation behaviour. Much attention has been also attracted by the related bond and site dilute Ising model, especially in two dimensions, leading to intriguing critical behavior.

See also

• Spin models
• Square-lattice Ising model
• Classical Heisenberg model
• Quantum Heisenberg model
• Kuramoto model
• XY model
• Potts model (common with Ashkin–Teller model)
• Maximal evenness
• Hopfield net
• Boltzmann machine
• ANNNI model
• Geometrically frustrated magnet
• t-J model
• Swendsen–Wang algorithm
• Wolff algorithm
• Ising critical exponents
• Conformal bootstrap
• J. C. Ward

External links

• Ising model at The Net Advance of Physics
• Barry A. Cipra, "The Ising model is NP-complete", SIAM News, Vol. 33, No. 6; online edition (.pdf)
• Science World article on the Ising Model
• A dynamical 2D Ising java applet by UCSC
• A dynamical 2D Ising java applet
• A larger/more complicated 2D Ising java applet
• An dynamical 2D Ising Model simulation
• Ising Model simulation by Enrique Zeleny, the Wolfram Demonstrations Project
• Phase transitions on lattices
• Three-dimensional proof for Ising Model impossible, Sandia researcher claims
• Equilibrium Statistical Mechanics of Classical Lattice Systems: a Concrete Introduction, Chapter 3 (The Ising model)
• Interactive Monte Carlo simulation of the Ising, XY and Heisenberg models with 3D graphics(requires WebGL compatible browser)
• Ising Model code , image denoising example with Ising Model